I would suggest you go here:
http://www.spudfiles.com/forums/search.html
Or straight to the Pneumatic Cannon Showcase section and look through cannons which have similar design features to yours, such as a 3/4" piston housing in a tee. Then you can see how other people did it
First Piston Valve Pneumatic
If by hold it you mean hold pressure, then yes teflon tape works great for that. Just make sure you drill a hole small enough that the threads dig into the pvc and leave grooves, it should take some effort to thread in the first time. I would suggest a threaded schrader valve like this one:
Why is there an o-ring between the washer and the 3/4" pipe on the left of the piston?
Why is there an o-ring between the washer and the 3/4" pipe on the left of the piston?
Well based on your drawing i assumed that you are using one of the conical reducers, not a reducing bushing, and that it would slip over the section of 3/4" pipe that would extend slightly out of the tee. In that case an o-ring would not be necessary, but if it is a bushing that is pushed into the tee then yes its very important.
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Mine's almost done. All I got to do is get the neoprene washer and put it on my piston, which I made (it's hot glue around a wine cork) then I have to glue the rest together. Most parts are already glued.