SiH<sub>4</sub> has an autoignition point of ~21°C in air, but you'd have one solid combustion product (SiO<sub>2</sub>) which would tend to reduce ballistic efficiency. B<sub>2</sub>H<sub>6</sub> autoignites at ~38°C, but suffers from the same problem. Aerosolized EGDN or PGDN would both decompose at just over 100°C, but that would be a terrible idea (all things considered, the previous two are just as terrible, but more proper to discuss on Spudfiles).still, does anybody know a material with a really low temperature autoignition point??
After that, we have diethyl ether at 160°C, and monomethyl hydrazine at just under 200°C. Pure hydrazine is in there somewhere as well. All of these are liquids at room temperature, but all but hydrazine have a flash point below room temperature. I have yet to come across a gas which would be suitable for your purpose.